P. R. SINGH, Balaji Jayaraman
Abstract
Abstract The reactions of sodium dihydronaphthylide with dichlorodiphenylmethane and 9,9-dichlorofluorene in THF at 0°C have been found to proceed by an electron transfer mechanism involving α-chloro radicals, vicinal-dichlorides and an equilibrating pair of classical and bridged β-chloro radicals.
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Abstract The reactions of sodium dihydronaphthylide with dichlorodiphenylmethane and 9,9-dichlorofluorene in THF at 0°C have been found to proceed by an electron transfer mechanism involving α-chloro radicals, vicinal-dichlorides and an equilibrating pair of classical and bridged β-chloro radicals.
Key concepts: Chemistry, Radical, Sodium, Medicinal chemistry, Organic chemistry