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2009•Journal of Heterocyclic ChemistryRequires access

Highly soluble perylene tetracarboxylic diimides (PDI)‐tetrathiafulvalene (TTF) dyad and TTF‐PDI‐TTF triad

Chengyun Wang, Wei Tang, Hanbin Zhong, Xuechao Zhang, Yongjia Shen

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Abstract

Abstract magnified image Two highly soluble donor‐σ‐acceptor and donor‐σ‐accepter‐σ‐donor type fluorescence switches consisting tetrathiafulvalene (TTF) and 3,4,9,10‐perylene tetracarboxylic diimides (PDI) were synthesized. The structure of the dyad and triad as well as their intermediates was characterized by 1H NMR, 13C NMR MS, elemental analysis. Their fluorescence behavior could be modulated by oxidization and reduction of the TTF unit using either chemical or electrochemical method. J. Heterocyclic Chem., (2009).

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What this paper is about

Abstract magnified image Two highly soluble donor‐σ‐acceptor and donor‐σ‐accepter‐σ‐donor type fluorescence switches consisting tetrathiafulvalene (TTF) and 3,4,9,10‐perylene tetracarboxylic diimides (PDI) were synthesized. The structure of the dyad and triad as well as their intermediates was characterized by 1H NMR, 13C NMR MS, elemental analysis. Their fluorescence behavior could be modulated by oxidization and reduction of the TTF unit using either chemical or electrochemical method. J. Heterocyclic Chem., (2009).

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Available abstract

Abstract magnified image Two highly soluble donor‐σ‐acceptor and donor‐σ‐accepter‐σ‐donor type fluorescence switches consisting tetrathiafulvalene (TTF) and 3,4,9,10‐perylene tetracarboxylic diimides (PDI) were synthesized. The structure of the dyad and triad as well as their intermediates was characterized by 1H NMR, 13C NMR MS, elemental analysis. Their fluorescence behavior could be modulated by oxidization and reduction of the TTF unit using either chemical or electrochemical method. J. Heterocyclic Chem., (2009).

Key concepts: Tetrathiafulvalene, Perylene, Chemistry, Triad (sociology), Fluorescence, Acceptor, Photochemistry, Proton NMR

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Highly soluble perylene tetracarboxylic diimides (PDI)‐tetrathiafulvalene (TTF) dyad and TTF‐PDI‐TTF triad — Research Paper | ScholarLens