Rate Constants for Reactions of Aliphatic Carbon-Centered Radicals in Aqueous Solution

Absolute rate constants for reactions of aliphatic carbon-centered radicals in aqueous solutions have been compiled and evaluated from the literature. Rate constants are included for reactions of radicals with inorganic and organic compounds and for decay by radical–radical reactions. The radicals were generated by radiolysis, photolysis, or other techniques, and their rate constants were determined generally by kinetic spectrophotometry. The tables include data for over 2,500 reactions of 373 radicals from 740 literature references.