Expanding the Versatility of Dipicolinate-Based Luminescent Lanthanide Complexes: A Fast Method for Antenna Testing
Julien Andrès, K. Eszter Borbas
Abstract
Julien Andrès, K. Eszter Borbas
Abstract
A dipicolinate (dpa)-based platform for the rapid testing of potential lanthanide-sensitizing antennae was developed; 4-methyl-7-O-alkylcoumarin-appended dpa could sensitize four lanthanides. The platform could be used to estimate the photophysical properties of a more difficult-to-prepare 1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid based structure carrying the same antenna.
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A dipicolinate (dpa)-based platform for the rapid testing of potential lanthanide-sensitizing antennae was developed; 4-methyl-7-O-alkylcoumarin-appended dpa could sensitize four lanthanides. The platform could be used to estimate the photophysical properties of a more difficult-to-prepare 1,4,7,10-tetraazacyclododecane-1,4,7-triacetic acid based structure carrying the same antenna.
Key concepts: Lanthanide, Chemistry, Antenna effect, Luminescence, Antenna (radio), Combinatorial chemistry, Nanotechnology, Organic chemistry