1961•Journal of the Chinese Chemical SocietyRequires access

Lithium Aryls. I. Preparation of p‐Cyclohexenyl‐Phenyllithium by Halogen‐Lithium Interconversion Reaction

Daniel Y. Chang, Ruey‐Jiin Yu

Abstract

Abstract The halogen‐lithium interconversion reaction between p‐bromophenyl‐cyclohexene‐1 and organolithium compounds was investigated. It resulted in the production of p‐Δ1‐cyclohexenyl‐phenyllithium. The organolithium compounds used in the interconversion reaction were phenyllithium, n‐propyllithium and n‐butyllithium. They brought about 25%, 19% and 10% conversions based on p‐bromophenylcyclohexene‐1 respectively.

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Available abstract

Key concepts: Phenyllithium, Chemistry, Organolithium compounds, Lithium (medication), Butyllithium, Halogen, Cyclohexene, Organic chemistry