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2015•Chemical CommunicationsRequires access

Toward electron-deficient pyrene derivatives: construction of pyrene tetracarboxylic diimide containing five-membered imide rings

Lin Zou, Xiaoye Wang, Xiao-Xiao Zhang, Ya‐Zhong Dai, Y.-T. Wu, Jie‐Yu Wang, Jian Pei

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Abstract

Electron-deficient pyrene-1,2,6,7-tetracarboxylic diimide () and its cyano derivative () have been designed and synthesized as a new family of aromatic diimides. PyrDI has two unexpected five-membered imide rings and can form excimers facilely in the solid state. These new pyrene derivatives are promising n-type semiconductors for organic electronics.

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What this paper is about

Electron-deficient pyrene-1,2,6,7-tetracarboxylic diimide () and its cyano derivative () have been designed and synthesized as a new family of aromatic diimides. PyrDI has two unexpected five-membered imide rings and can form excimers facilely in the solid state. These new pyrene derivatives are promising n-type semiconductors for organic electronics.

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Available abstract

Electron-deficient pyrene-1,2,6,7-tetracarboxylic diimide () and its cyano derivative () have been designed and synthesized as a new family of aromatic diimides. PyrDI has two unexpected five-membered imide rings and can form excimers facilely in the solid state. These new pyrene derivatives are promising n-type semiconductors for organic electronics.

Key concepts: Diimide, Imide, Pyrene, Chemistry, Photochemistry, Derivative (finance), Polymer chemistry, Materials science

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