2002•Chemical CommunicationsRequires access

1,5-Bis(benzothiazolyl)-3-thiapentane and its asymmetric dinuclear Ag(i) complex with three distinct intermolecular-stacking interactionsElectronic supplementary information (ESI) available: 3D rotatable structures of 2 and 3. See http://www.rsc.org/suppdata/cc/b2/b204843d/

Craig A. Grapperhaus, Ming Li, Mark S. Mashuta

Abstract

Synthesis of a dibenzothiazole thioether ligand that coordinates Ag(I) yielding an asymmetric dinuclear complex with three unique intermolecular pi-stacking interactions, which influence the first coordination spheres of the silver centers, is reported.

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Key concepts: Stacking, Intermolecular force, Thioether, Crystallography, Ligand (biochemistry), Chemistry, Stereochemistry, Molecule