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1997•Zeitschrift für Kristallographie - Crystalline MaterialsRequires access

The crystal structure of lithiumpentamolybdate Li4Mo5O17

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Abstract

Abstract Lithiumpentamolybdate has been characterized by X-ray single crystal structure analysis (300 K). Li4Mo5O17, Mr = 779.45, triclinic, P[unk], a = 6.7775(1) Å, b = 9.461(1) Å, c = 10.802(2) Å, α = 73.16(2)°, β = 88.98(1)°, γ = 69.760(2)°, V = 619.2(2) Å3, Z = 2, Dx = 4.181 g cm−3, λ(MoKα ) = 0.71069 Å. The structure consists of stripes of MoO6-octahedra linked together by distorted LiO4-tetrahedra and LiO6-octahedra to form a three-dimensional network.

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Abstract Lithiumpentamolybdate has been characterized by X-ray single crystal structure analysis (300 K). Li4Mo5O17, Mr = 779.45, triclinic, P[unk], a = 6.7775(1) Å, b = 9.461(1) Å, c = 10.802(2) Å, α = 73.16(2)°, β = 88.98(1)°, γ = 69.760(2)°, V = 619.2(2) Å3, Z = 2, Dx = 4.181 g cm−3, λ(MoKα ) = 0.71069 Å. The structure consists of stripes of MoO6-octahedra linked together by distorted LiO4-tetrahedra and LiO6-octahedra to form a three-dimensional network.

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Available abstract

Abstract Lithiumpentamolybdate has been characterized by X-ray single crystal structure analysis (300 K). Li4Mo5O17, Mr = 779.45, triclinic, P[unk], a = 6.7775(1) Å, b = 9.461(1) Å, c = 10.802(2) Å, α = 73.16(2)°, β = 88.98(1)°, γ = 69.760(2)°, V = 619.2(2) Å3, Z = 2, Dx = 4.181 g cm−3, λ(MoKα ) = 0.71069 Å. The structure consists of stripes of MoO6-octahedra linked together by distorted LiO4-tetrahedra and LiO6-octahedra to form a three-dimensional network.

Key concepts: Triclinic crystal system, Octahedron, Crystallography, Crystal structure, Tetrahedron, Chemistry, Materials science

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