Effects of breaking gravity waves on the chemical composition of the mesosphere and lower thermosphere

Eddy diffusion and momentum forcing in the mesosphere and lower thermosphere arise principally from the effects of breaking gravity and waves. The propagation and dissipation of gravity waves depend strongly on season and latitude because of its relationship to the background zonal wind. These processes have significant effects on the transport of chemical species in that region, so that observations of variations in chemical constituents provide useful tracers for dynamical theory. A parameterization of gravity wave propagation and dissipation was incorporated in the coupled dynamical-chemical model to study these effects. Several easily observable airglow features of the mesosphere-thermosphere region are shown to provide sensitive indications of gravity wave influence. In particular, theoretical predictions of large seasonal and latitudinal variations in the atomic oxygen green line, the Meinal bands of excited OH, and the O3 densities inferred from O2 (delta supra 1 sub g) emission at altitudes from 75 to 90 km are shown to be in remarkably good agreement with observations. Implications of these sensitive chemical tracers for the dynamics of the mesosphere-lower thermosphere region and its relationship to gravity waves are discussed.