Constraints on chondrule and CAI origins from vapor-liquid-solid experiments

It has been widely accepted that evaporation played an important role in the formation of chondritic constituents and elemental and isotopic fractionation in the solar nebula. Although many workers consider that evaporation is just the opposite of condensation, it is true only when the process is in equilibrium. When the process is not in equilibrium, e.g., local evaporation, where generated gas moves away from the residual solids, the fractionation path is quite different from the opposite of condensation of the gas with the solar system elemental abundances. The degree of elemental, particularly isotopic, fractionation is strongly dependent on the evaporation rate of the element when evaporation takes place from solid materials. The phase relations and the rate of evaporation of chondrite-forming minerals give constraints on partial pressure of the dust components, total pressure of the nebular gas, and heating rate of the materials.