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2003•Fullerenes Nanotubes and Carbon NanostructuresRequires access

Reaction Kinetics of C60Fullerene Ozonation

M. P. Anachkov, Franco Cataldo, Slavtcho K. Rakovsky

Open publisher page 15 citations

Abstract

It has been verified that the reaction between O3 and C60 follows the general second order reaction rate which is valid for all the reactions between ozone and unsaturated olefinic bonds: v = k[C˭C][O3]. The reaction rate constant k has been measured ≈(1.5 ± 0.3) × 104 L mol−1 s−1. The value of this rate constant has the same order of magnitude of the rate constant measured for instance in the ozonation of 1,4‐diphenylbutadiene.

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What this paper is about

It has been verified that the reaction between O3 and C60 follows the general second order reaction rate which is valid for all the reactions between ozone and unsaturated olefinic bonds: v = k[C˭C][O3]. The reaction rate constant k has been measured ≈(1.5 ± 0.3) × 104 L mol−1 s−1. The value of this rate constant has the same order of magnitude of the rate constant measured for instance in the ozonation of 1,4‐diphenylbutadiene.

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Available abstract

It has been verified that the reaction between O3 and C60 follows the general second order reaction rate which is valid for all the reactions between ozone and unsaturated olefinic bonds: v = k[C˭C][O3]. The reaction rate constant k has been measured ≈(1.5 ± 0.3) × 104 L mol−1 s−1. The value of this rate constant has the same order of magnitude of the rate constant measured for instance in the ozonation of 1,4‐diphenylbutadiene.

Key concepts: Reaction rate constant, Ozone, Chemistry, Kinetics, Fullerene, Order of reaction, First order, Reaction rate

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