2008Unpublished venueRequires access

Heterolytic σ ‐Bond Activation by Transition Metal Complexes

Shigeyoshi Sakaki, Noriaki Ochi, Yu‐ya Ohnishi

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Abstract

This chapter contains sections titled: Introduction Characteristic Features of Heterolytic σ-Bond Activation Theoretical Study of the Shilov Reaction Fujiwara–Moritani Reaction: Driving Force and Orbital Interaction Heterolytic CH σ-Bond Activation of Methane Methane CH Bond Activation by Pt(II) Complexes Methane CH Bond Activation by Late Transition Metal Catalysts Heterolytic Methane CH Bond Activation by Early Transition Metal Systems Heterolytic σ-Bond Activation of Dihydrogen and Alcohol Molecules Heterolytic HH Bond Activation Heterolytic σ-Bond Activation in Hydrogen Transfer Reactions Summary References

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What this paper is about

This chapter contains sections titled: Introduction Characteristic Features of Heterolytic σ-Bond Activation Theoretical Study of the Shilov Reaction Fujiwara–Moritani Reaction: Driving Force and Orbital Interaction Heterolytic CH σ-Bond Activation of Methane Methane CH Bond Activation by Pt(II) Complexes Methane CH Bond Activation by Late Transition Metal Catalysts Heterolytic Methane CH Bond Activation by Early Transition Metal Systems Heterolytic σ-Bond Activation of Dihydrogen and Alcohol Molecules Heterolytic HH Bond Activation Heterolytic σ-Bond Activation in Hydrogen Transfer Reactions Summary References

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Available abstract

This chapter contains sections titled: Introduction Characteristic Features of Heterolytic σ-Bond Activation Theoretical Study of the Shilov Reaction Fujiwara–Moritani Reaction: Driving Force and Orbital Interaction Heterolytic CH σ-Bond Activation of Methane Methane CH Bond Activation by Pt(II) Complexes Methane CH Bond Activation by Late Transition Metal Catalysts Heterolytic Methane CH Bond Activation by Early Transition Metal Systems Heterolytic σ-Bond Activation of Dihydrogen and Alcohol Molecules Heterolytic HH Bond Activation Heterolytic σ-Bond Activation in Hydrogen Transfer Reactions Summary References

Key concepts: Heterolysis, Chemistry, Transition metal, Catalysis, Methane, Photochemistry, Organic chemistry

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