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Application of Scanning Tunneling Microscopy to Studies of Electrode Surfaces

Allen J. Bard

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Abstract

This project involved the study of a variety of different surfaces and structures in gaseous and liquid environments using the scanning tunneling microscope (STM) and other scanning probe microscopes with the aim of obtaining a better understanding of electrode surfaces and the processes occuring on these surfaces. With the STM we investigated chemical changes on the surface of electrodes, e.g., corrosion, passivation, and biochemical activities, and studied the energetics for electron transfer at the surfaces of semiconductors. We also investigated nanostructures (for example, very small semiconductor particles, porous Si, and self-assembled monolayers) using this technique. Scanning tunneling microscopy (STM), Scanning probe microscopy (SPM), Semiconductor surfaces, Electrode surfaces, Nanostructures

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What this paper is about

This project involved the study of a variety of different surfaces and structures in gaseous and liquid environments using the scanning tunneling microscope (STM) and other scanning probe microscopes with the aim of obtaining a better understanding of electrode surfaces and the processes occuring on these surfaces. With the STM we investigated chemical changes on the surface of electrodes, e.g., corrosion, passivation, and biochemical activities, and studied the energetics for electron transfer at the surfaces of semiconductors. We also investigated nanostructures (for example, very small semiconductor particles, porous Si, and self-assembled monolayers) using this technique. Scanning tunneling microscopy (STM), Scanning probe microscopy (SPM), Semiconductor surfaces, Electrode surfaces, Nanostructures

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Available abstract

This project involved the study of a variety of different surfaces and structures in gaseous and liquid environments using the scanning tunneling microscope (STM) and other scanning probe microscopes with the aim of obtaining a better understanding of electrode surfaces and the processes occuring on these surfaces. With the STM we investigated chemical changes on the surface of electrodes, e.g., corrosion, passivation, and biochemical activities, and studied the energetics for electron transfer at the surfaces of semiconductors. We also investigated nanostructures (for example, very small semiconductor particles, porous Si, and self-assembled monolayers) using this technique. Scanning tunneling microscopy (STM), Scanning probe microscopy (SPM), Semiconductor surfaces, Electrode surfaces, Nanostructures

Key concepts: Scanning tunneling microscope, Scanning electron microscope, Electrochemical scanning tunneling microscope, Scanning probe microscopy, Electrode, Scanning ion-conductance microscopy, Materials science, Semiconductor

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