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On the proton affinity of peroxynitrite and peroxynitrous acid

Saša Kazazić, Snježana Kazazić, L. Klasinc̆, S. P. McGlynn, William A. Pryor

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Abstract

The proton affinity (PA) of peroxynitrite (ONOO -) and peroxynitrous acid (ONOOH) are calculated to be 1440.5 kJ mol -1 and 749.8 kJ mol -1 , respectively.Comparison with results for the nitrous, nitric and peroxynitric acid and their anions supports these estimates.

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The proton affinity (PA) of peroxynitrite (ONOO -) and peroxynitrous acid (ONOOH) are calculated to be 1440.5 kJ mol -1 and 749.8 kJ mol -1 , respectively.Comparison with results for the nitrous, nitric and peroxynitric acid and their anions supports these estimates.

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Available abstract

The proton affinity (PA) of peroxynitrite (ONOO -) and peroxynitrous acid (ONOOH) are calculated to be 1440.5 kJ mol -1 and 749.8 kJ mol -1 , respectively.Comparison with results for the nitrous, nitric and peroxynitric acid and their anions supports these estimates.

Key concepts: Peroxynitrite, Peroxynitrous acid, Chemistry, Nitric acid, Nitrous acid, Proton, Proton affinity, Inorganic chemistry

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