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The Isolation and Properties of Curium

Louis Werner

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Abstract

The isolation of curium, element number 96, in relatively pure form has been accomplished. A method, involving a solvent extraction process, is given for the purification of americium from lanthanum and other ions. The discovery of a higher oxidation state of americium led to a method of separating americium from curium. Separation of the two elements was also accomplished by use of ion exchange resins. The details of the isolation of curium are given; the results of the spectrographic analysis, specific activity measurement, and calorimetric determination of half life showed the curium to be relatively pure. The absorption of light of various wave-lengths by an aqueous solution of Cm(III) is described, and some physical effects of the radiation from the curium are noted.

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The isolation of curium, element number 96, in relatively pure form has been accomplished. A method, involving a solvent extraction process, is given for the purification of americium from lanthanum and other ions. The discovery of a higher oxidation state of americium led to a method of separating americium from curium. Separation of the two elements was also accomplished by use of ion exchange resins. The details of the isolation of curium are given; the results of the spectrographic analysis, specific activity measurement, and calorimetric determination of half life showed the curium to be relatively pure. The absorption of light of various wave-lengths by an aqueous solution of Cm(III) is described, and some physical effects of the radiation from the curium are noted.

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Available abstract

The isolation of curium, element number 96, in relatively pure form has been accomplished. A method, involving a solvent extraction process, is given for the purification of americium from lanthanum and other ions. The discovery of a higher oxidation state of americium led to a method of separating americium from curium. Separation of the two elements was also accomplished by use of ion exchange resins. The details of the isolation of curium are given; the results of the spectrographic analysis, specific activity measurement, and calorimetric determination of half life showed the curium to be relatively pure. The absorption of light of various wave-lengths by an aqueous solution of Cm(III) is described, and some physical effects of the radiation from the curium are noted.

Key concepts: Curium, Americium, Chemistry, Californium, Lanthanum, Radiochemistry, Solvent extraction, Extraction (chemistry)

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