1973•OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information)Requires access

Radicals in $gamma$-irradiated adamantane with admixtures of cyclopentane and tetrahydrofuran

A.P. Kuleshov, Vladimir Ivanovich Trofimov

Open publisher page 0 citations

Abstract

The EPR spectra of pure adamantane and adamantane with admixtures of cyclopentane and tetrahydrofuran, gamma -irradiated at --196 deg , were measured. With increasing temperature the appearance of new lines in the spectra is observed. These are secondary radicals originating from the primary adamantane radicals. The dependence of the frequency of exchange on temperature was established. (JSR)

About this research paper

What this paper is about

The EPR spectra of pure adamantane and adamantane with admixtures of cyclopentane and tetrahydrofuran, gamma -irradiated at --196 deg , were measured. With increasing temperature the appearance of new lines in the spectra is observed. These are secondary radicals originating from the primary adamantane radicals. The dependence of the frequency of exchange on temperature was established. (JSR)

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

The EPR spectra of pure adamantane and adamantane with admixtures of cyclopentane and tetrahydrofuran, gamma -irradiated at --196 deg , were measured. With increasing temperature the appearance of new lines in the spectra is observed. These are secondary radicals originating from the primary adamantane radicals. The dependence of the frequency of exchange on temperature was established. (JSR)

Key concepts: Cyclopentane, Radical, Adamantane, Tetrahydrofuran, Electron paramagnetic resonance, Chemistry, Spectral line, Photochemistry

Related papers

Back to paper searchBrowse research topicsOriginal source
Radicals in $gamma$-irradiated adamantane with admixtures of cyclopentane and tetrahydrofuran — Research Paper | ScholarLens