Radicals in $gamma$-irradiated adamantane with admixtures of cyclopentane and tetrahydrofuran
A.P. Kuleshov, Vladimir Ivanovich Trofimov
Abstract
A.P. Kuleshov, Vladimir Ivanovich Trofimov
Abstract
The EPR spectra of pure adamantane and adamantane with admixtures of cyclopentane and tetrahydrofuran, gamma -irradiated at --196 deg , were measured. With increasing temperature the appearance of new lines in the spectra is observed. These are secondary radicals originating from the primary adamantane radicals. The dependence of the frequency of exchange on temperature was established. (JSR)
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The EPR spectra of pure adamantane and adamantane with admixtures of cyclopentane and tetrahydrofuran, gamma -irradiated at --196 deg , were measured. With increasing temperature the appearance of new lines in the spectra is observed. These are secondary radicals originating from the primary adamantane radicals. The dependence of the frequency of exchange on temperature was established. (JSR)
Key concepts: Cyclopentane, Radical, Adamantane, Tetrahydrofuran, Electron paramagnetic resonance, Chemistry, Spectral line, Photochemistry