1980•The Knowledge Bank (The Ohio State University)Requires access

MILLIMETER ROTATIONAL SPECTROSCOPY AS A DIAGNOSTIC PROBE OF THE CHEMICAL REACTIONS AND ROTATIONAL, TRANSLATIONAL, AND VIBRATIONAL TEMPERATURES IN AN OCS $DISCHARGE^{*}$

William W. Clark, Frank C. De Lucia

Open publisher page 0 citations

Abstract

Millimeter wave rotational spectroscopy is described as a diagnostic probe for DC and pulsed discharges in OCS. Tests for rotational equilibria are discussed and the results of these tests as applied to the OCS discharge system described. Rotational, translational, and vibrational temperature have been measured and their time evolution related to diffusion times in the system. Chemical decomposition was studied by Lie monitoring of OCS, CO, CS, and SO spectra in several vibrational states and by chemical analysis of the discharge products deposited on toe wall.

About this research paper

What this paper is about

Millimeter wave rotational spectroscopy is described as a diagnostic probe for DC and pulsed discharges in OCS. Tests for rotational equilibria are discussed and the results of these tests as applied to the OCS discharge system described. Rotational, translational, and vibrational temperature have been measured and their time evolution related to diffusion times in the system. Chemical decomposition was studied by Lie monitoring of OCS, CO, CS, and SO spectra in several vibrational states and by chemical analysis of the discharge products deposited on toe wall.

Why it matters

A significance statement is not available in the OpenAlex record.

Key contribution

A contribution statement is not available in the OpenAlex record.

Method / approach

Method details are not available in the OpenAlex metadata.

Main findings

Findings are not separately available in the OpenAlex metadata.

Limitations

Limitations are not available in the OpenAlex metadata.

Applications

Application details are not available in the OpenAlex metadata.

Available abstract

Millimeter wave rotational spectroscopy is described as a diagnostic probe for DC and pulsed discharges in OCS. Tests for rotational equilibria are discussed and the results of these tests as applied to the OCS discharge system described. Rotational, translational, and vibrational temperature have been measured and their time evolution related to diffusion times in the system. Chemical decomposition was studied by Lie monitoring of OCS, CO, CS, and SO spectra in several vibrational states and by chemical analysis of the discharge products deposited on toe wall.

Key concepts: Rotational spectrum, Millimeter, Rotational–vibrational spectroscopy, Rotational temperature, Spectroscopy, Rotational spectroscopy, Rotational transition, Chemistry

Related papers

Back to paper searchBrowse research topicsOriginal source